Step 1: Preheat and prepare the pan
Preheat your oven to 170°C / 338°F (conventional). Line a baking sheet with parchment paper. Make sure your eggs are at room temperature before you start.
Step 2: Melt the chocolate and butter
Place the chopped dark chocolate and butter in a heatproof bowl. Melt gently over a pan of barely simmering water, stirring often, or microwave in short 20–30 second bursts, stirring between each, until smooth and glossy. Set aside to cool slightly; it should be warm, not hot.
Step 3: Whip the eggs and sugars
In a large mixing bowl, add the eggs, caster (or granulated) sugar, and demerara sugar. Using an electric hand mixer or stand mixer, beat on high speed for 4–5 minutes until the mixture is very pale, thick, and fluffy. When you lift the beaters, the mixture should fall back in thick ribbons that sit on the surface for a few seconds before slowly sinking in. This step helps create thick, fudgy brookies with shiny crackly tops.
Step 4: Combine with the melted chocolate
With the mixer on low speed, slowly pour the melted chocolate and butter into the whipped egg mixture. Mix just until combined and no streaks remain. Stir in the vanilla extract.
Step 5: Add the dry ingredients
In a separate bowl, whisk together the flour, cocoa powder, baking powder, and salt. Add the dry mixture to the chocolate mixture. Using a spatula, gently fold until no dry streaks of flour remain. Do not overmix. Fold in the chocolate chips, if using. The batter will be thick and glossy.
Step 6: Scoop and bake
Use a cookie scoop or tablespoon to portion the batter onto the prepared baking sheet, about 1 heaping tablespoon (roughly 25–30 g) per cookie. Space the mounds 2–3 inches apart; you should get about 14–16 cookies. Bake for 12–14 minutes, until the tops are shiny and crackled and the edges look set while the centers still appear soft.
Step 7: Cool and set
Remove the baking sheet from the oven and let the brookies cool on the tray for about 10 minutes. They will firm up as they cool. Transfer carefully to a wire rack to cool completely, or enjoy slightly warm for extra gooey centers. For fan/convection ovens, reduce the temperature to about 160°C / 320°F and start checking a minute or two earlier.